First, an explanation of how the diagram is built up is given, and then its use is describ ed. Sherpha project transcritical r744 heat pumps technicians manual 862 1. Explanations of ph diagram refrigerant characteristics table. Fundamentals of refrigeration li 001 v3 fundamentals of refrigeration. Similarly, the expansion device is characterized by the suction and discharge pressures. The pressureenthalpy diagram or p h diagram is a tool that all hvac and refrigeration engineers should be able to use proficiently. The vapor is compressed, following the constant entropy line to. This diagram describes the relationship of pressure and enthalpy of a select refrigerant. Case1 the basics of refrigeration cycle ph diagram analysis. Appendix b log ph diagrams for refrigerants experts in brazed plate heat exchangers swep is a worldleading supplier of brazed plate heat exchangers for hvac and industrial applications. Po box, the heath, runcorn, cheshire, wa7 4qx tele. Figuring out the vapor fraction in a ln ph diagram.
Ts diagram of stirling cycles a and ericsson cycles b. Figuring out the vapor fraction in a ln p h diagram. Based on thermodynamic properties of hfc4a 2 tetra. Pdf plotting of ph and ts diagrams of fluoropropylenes. How can i plot the p h diagram for my system using ees software. The pressureenthalpy diagram or ph diagram is a tool that all hvac and refrigeration engineers should be able to use proficiently. This definition of enthalpy can be expressed, mathematically, as follows. The pressureenthalpy diagram log p h diagram is a very useful tool for refrigerant technicians. With thermodynamic properties that are very similar to those of r4a, isobutane was used in germany as early as 1992 to replace r12. Huber national institute of standards and technology, marcia. Thermodynamic properties saturation table 1415 contents. Fluoropropylenes, pressureenthalpy diagram, temperatureentropy diagram.
May 25, 2019 r4a is the most common refrigerant found in automobiles today. Evaluation of hfo1234yf as a potential replacement for r4a in refrigeration. The pressureenthalpy ph diagram is a useful tool for refrigeration engineers and designers. Pressure enthalpy diagram melting line40 o 40 c2 02 0 t 0 o c 0 0 20 40 40 60 60 80 80 100 100 120 120 140 140 160 160 180 180 200 200 220 220.
Based on the program allprops, center for applied thermodynamic studies, university of idaho. This dependency can be seen on the pressureenthalpy diagram. Danfoss light commercial refrigeration compressors b, u, l, p, x, s ranges 60hz. Isobaric, isochoric and supercritical thermal energy storage in r4a. By knowing the zone divided with saturation curve in which the intersection point of pressure. Light commercial refrigeration compressors b, u, l, p, x.
The ph diagram of the refrigeration cycle with all the operating conditions are as the following. An isotherm, or equal temperature line, has a downward slope until is hits the liquidvapor dome. The content and the intellectual layout in this chart are property of nrf bv. Plotting of ph and ts diagrams of fluoropropylenes. Thermodynamic properties of hfc4a reading advantage 3 pdf refrigerant. In the log ph diagram the pressure p is plotted above the p.
Thermodynamics enthalpy entropy mollier and steam tables i. Mclinden thermophysics division national institute of standards and technology. That being said, there are still millions of cars on the road that. Plotting of p h and ts diagrams of fluoropropylenes. Positively innovative refrigerants r32 daikin chemical europe. Modified rankine cycle on p v diagram for steam engines. Properties of refrigerant r22 saturated liquid and saturated vapor both imperial. A cyclic process can be represented very clearly in the ts diagram. R4a is the most common refrigerant found in automobiles today. Cops of r718 in comparision with other modern refrigerants a.
In the past the most popular fluids have been ammonia r717,fluorocarbons and halo carbons. New tables of the thermodynamic properties of hfc4a have been. How can i plot the ph diagram for my system using ees. In order to properly understand this diagram, it is best to go through the vapor compression cycle on a p h diagram. R4a refrigerant pressure temperature chart refrigerant hq. The characteristics of temperature gradients for pressure and enthalpy are shown on p h diagrams, called isothermal lines. Since this is a ln pressureenthalpy graph, the enthalpy is marked on the xaxis. A pressure enthalpy graph is individual for each refrigerant. The points on these curves indicate the pressure and corresponding temperatures under which two different phases can exist in equilibrium e. An overview of cptes in r4a is given by the ht diagram in figure 2. Like the pn diagram, there are regions on a ph diagram in which two phases exist together. Modified rankine cycle on pv diagram for steam engines. Use the ph diagram analysis, all the refrigerant flow rates and operating conditions at the design point for the system can be clearly determined.
Entropy is the measure of the amount of disorder in the system. It has been in use since the early 1990s and now, in 2019, we are beginning to see its popularity wane with the rise of the new hfo refrigerant known as r1234yf. Temperature is slightly harder to read than other properties. The input and output format was aloo changed to yield. Bookmark this page email this page download this page as pdf print this page facebook. Download a pdf copy of the pressure enthalpy chart for both metric and imperial units. Once the line hits the liquidvapor dome, the isotherm has no slope and is horizontal. Coolpack was developed by the department of mechanical engineering mek, section of thermal energy tes at the technical university of denmark dtu. Figure a15 nelsonobert generalized compressibility chart.
Thermodynamic properties of rl34a l,1,1,2tetrafluoroethane 1 marcia l. R22 properties of r22 vapor volume, enthalpy and entropy at pressures. Pdf the report addresses issues of plotting the pressureenthalpy and temperatureentropy. Danfoss light commercial refrigeration compressors frcc. An r4a refrigeration system condenses at 95 f and evaporates at 45 f. Positively innovative r32 instructions for use and handling refrigerants r32. A ph diagram can be constructed for any pure substance.
Pressure enthalpy diagram melting line40 o 40 c2 02 0. Enthalpy is also considered to be the sum of internal energy u and flow energy or flow work p. A suitable range of the mollier chart has been selected for actual. Thermodynamic properties of r4a 1,1,1,2tetrafluoroethane. The design is to be based upon the ideal vaporcompression refrigeration cycle, with four components. R4a pressure enthalpy chart the engineering mindset.
The ph diagram is a graphical representation of the refrigerant as it travels through the refrigeration system. A pressure enthalpy ph diagram exhibits the same features as a pn diagram. Refrigeration cycle refrigeration is the transfer of heat from a lower temperature region to a higher temperature region refrigeration cycle is the vaporcompression refrigeration cycle, where the refrigerant is vaporized and condenses alternately and is compressed in the vapor phase. Ph diagram is to analysis the feasibility of the refrigeration cycle, to calculate the thermodynamic properties of the refrigeration system. Refrigerants such as r4a have been developed and are now included in the. The vapor is compressed, following the constant entropy line to the pressure cor.
The areas between the curves define the limits of temperature and pressure at which different phases can exist. This case is also to evaluate various cycles such as with penalties, economizing for a. How can i plot the ph diagram for my system using ees software. Manual for refrigeration servicing introduction technicians. Isobaric, isochoric and supercritical thermal energy storage in r4a benjamin i. The performance of the heat pump cycle using the binary refrigerant mixture r4a r123 was. In order to properly understand this diagram, it is best to go through the vapor compression. Isobutane r600a isobutane is a hydrocarbon, and hence is flammable. Enthalpy kjkg 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 540 560 pressure bar 0. The comparison is based on coefficient of performance cop obtained by the refrigerant in the refrigeration cycle, and various cycle parameters. H figure 14 ph diagram for basic refrigeration circuit the expansion device is between points 4 and 1. Enthalpy kjkg 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 540 560 pressure bar 0,50 0,60 0,70 0,80 0,90 1,00.
More displacement, more efficient, compactness range. For single refrigerants such as r22 and r4a, the isot hermal line has no gradient in the saturated area, that is, the saturation temperature under certain pressure is the same at both the liquid side and the gas side. Welcome to the manual for refrigeration servicing technicians. It raises the pressure, temperature and enthalpy of the refrigerant by compressing the saturated gas, in an isentropic process, to a superheated. Conditioning and refrigeration relations, tables and charts. The compressor does work on the refrigeration system consumes energy. The saturated vapor entering the compressor suction would be at 20. Thermodynamic properties of r4a 1,1,1,2tetrafluoroethane m.